Depending on your settings, your PHEV may have the engine running to supply cabin heat. As a quick check on that idea, turn the HVAC off. That may not work if you also have auto defog enabled (which it is by default) as that needs heat and AC to work (the AC will be in stealth mode, the light will not be on). You can toggle defog with a long press on the front defrost button - a dialog will pop up and let you know which mode you just switched to.
For what it is worth, I toggled my auto defog to off shortly after I bought it and have never felt the need and the idea of running AC just feels wrong (one can still manually turn on the AC). And Hyundai/Kia is wrong for hiding that the AC is on with auto defog.
Typically unless it is really cold, I can manage any windshield fog with a bit of fan (just like the old days when I had no AC). Mind you, I have the HEV so no choice about engine coming on, so I'm covered after a few minutes in really cold weather with warm air to windshield. Which my car will experience for the first time tomorrow morning with a predicted 8F below zero.